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NAVAL POSTGRADUATE SCHOOL 

Monterey, California 




THERMO ECONOMIC ANALYSIS OF VAPOR POWER SYSTEMS 

by 

CDR F. L. Sheppard, Jr., USN 
J. K. Hartman 
M. D. Kelleher 
R. H. Nunn 



30 June 1975 



Approved for public release; distribution unlimited. 



FEDDOCS 
D 208.14/2: 
NPS-59NN75062A 




NAVAL POSTGRADUATE SCHOOL 
Monterey, California 



Rear Admiral Isham Linder J. R. Borsting 

Superintendent Provost 



THERMOECONOMIC ANALYSIS OF 
VAPOR POWER SYSTEMS 



A method is presented for determining the 
relationships between the costs and technical per- 
formance of vapor power systems in a manner which 
permits fundamental design specifications to be 
made optimally with respect to overall system life- 
time costs. Means of applying optimization tech- 
niques for large scale systems to the thermoeconomic 
analysis of vapor power systems are described and 
demonstrated with a simplified sample model. The 
example studied is an environmentally driven ocean 
thermal gradient system. A sequential unconstrain- 
ed minimization algorithm is employed for overall 
system design optimization. 



The work reported herein has been supported by the 
Energy Programs Office, Code L80, of the Civil 
Engineering Laboratory, Port Hueneme, California; 
work request N68305 75 WR-S-0068. 



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3. RECIPIENT'S CATALOG NUMBER 


■4. TITLE (end Subtitle) 

THERM0EC0N0MIC ANALYSIS OF VAPOR POWER SYSTEMS 


5. TYPE OF REPORT & PERIOD COVERED 

FINAL, FY75 


6. PERFORMING ORG. REPORT NUMBER 


7. AUTHOR (a) 

F. L. Sheppard, J. K. Hartman, M. D. Kelleher, 
R. H. Nunn 


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Naval Postgraduate School 
Monterey, CA 93940 


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N68305 75 WR-5-0068 


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Civil Engineering Laboratory 
Naval Construction Battalion Center 
Port Hueneme, CA 93043 


12. REPORT DATE 

30 Jun 75 


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106 


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Approved for public release; distribution unlimited. 


17. DISTRIBUTION STATEMENT (of the abetted entered in Biock 20, it different from Report) 


18. supplementary notes 


19. KEY WORDS (Continue on reveree side if neceeeary end identify by block number) 

Engineering Economics, Thermoeconomics , Thermodynamics, Optimization. 


20. ABSTRACT (Continue on reveree eide if neceeeary and identify by biock number) 

A method is presented for determining the relationships between 
the costs and technical performance of vapor power systems in a 
manner which permits fundamental design specifications to be 
made optimally with respect to overall system lifetime costs. 

Means of applying optimization techniques for large scale systems 
to the thermoeconomic analysis of vapor power systems are described 



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UU 1 JAN 73 



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20. (continued) and demonstrated with a simplified sample model. 

The example studied is an environmentally driven ocean thermal gradient 
system. A sequential unconstrained minimization algorithm is employed 
for overall systen design optimization. 



DD Form 1473 (BACK) 
. 1 Jan 73 

S/N 0102-014-6601 



4 



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TABLE OF CONTENTS 



I. INTRODUCTION 12 

A. BACKGROUND 12 

B. THERMOECONOMICS 17 

C. OBJECTIVE 19 

II. THERMOECONOMIC ANALYSIS 21 

A. CONCEPT 21 

B. PROBLEM REDUCTION 21 

C. PROBLEM COORDINATION 2 3 

III. SAMPLE ANALYSIS 2 9 

A. PRELIMINARIES 2 9 

B. BASIC SYSTEM DESCRIPTION 2 9 

C. DETAILED DESCRIPTION OF ZONE 1 34 

D. SOLUTION ALGORITHM 4 2 

E. INITIAL COMPUTATIONAL CONSIDERATIONS 4 5 

F. FIRST ZONE 1 SOLUTION 46 

G. TESTING THE SOLUTION 50 

H. ACCELERATION PROCEDURES 5 3 

I. LINKING VARIABLE BEHAVIOR 54 

J. ZONE VARIABLE BEHAVIOR 5 7 

K. ZONE 1 SUMMARY 6 6 

L. ZONE 2 ANALYSIS 6 6 

M. COMPLETION OF THE ANALYSIS 68 

IV. SUMMARY AND CONCLUSIONS 7 0 

APPENDIX A - MODEL DEVELOPMENT 74 



5 



APPENDIX B - EXTENSION TO REAL SYSTEM 



79 



APPENDIX C - DATA 83 

COMPUTER PROGRAM 98 

REFERENCES 101 

INITIAL DISTRIBUTION LIST 104 



6 



LIST OF TABLES 



Table 


III-l. 


Table 


III-2 . 


Table 


III-3 . 


Table 


III-4 . 


Table 


Ill- 5 . 


Table 


III-6 . 


Table 


III-7 . 


Table 


III-8 . 


Table 


III-9 . 


Table 


III-10 


Table 


IV-1. 



Fluid Properties 

Selected Values of Parameters 

First Zone 1 Solution 

Initial X Vectors 
o 

Fouling Factor Cost Effects 
Dimensional Constraint Cost Effects 
Cost Sensitivity to Modeling Equations 
Improved Parameter Selections 
Improved Zone 1 Solution 
Results With Alternate Working Fluids 
Summary of Design Evolution 



Appendix 



Table 1 
Table 2 
Table 3 
Table 4 



Appendix C 
Appendix C 
Appendix C 
Appendix C 



Results of T^ Investigation 
Results of d Investigation 
Results of Rp Investigation 
Results of Dimensional Constraint 
Investigation 



7 



LIST OF FIGURES 



1. Vapor cycle diagram 12 

2. Closed Rankine Cycle 14 

3. Waste heat cycles 16 

4. Model Coordination 25 

5. Goal Coordination 2 7 

6. Basic System 30 

7. Heat Exchanger 32 

8. T„ vs Cost, T = 5 5°F 56 

9. T u vs Cost, T = 5 0°F , 55°F 58 

n C 

10. Cost vs Tube Diameter 60 

11. Dimensional Constraint Effects 63 



8 



LIST OF SYMBOLS 



Material Properties Units 



p 


working fluid density 


lbm/ft 2 


P H 


seawater density 


lbm/ft 2 


C 

D 


working fluid heat capacity 


Btu/lbm-°F 


r 

C u 
pH 


seawater heat capacity 


Btu/lbm-°F 


y 


working fluid viscosity 


lbm/ft-hr 


y H 


seawater viscosity 


lbm/ft-hr 


k 


working fluid conductivity 


Btu/hr-ft-°F 


k H 


seawater conductivity 


Btu/hr-ft-°F 


k 

w 


tube wall conductivity 


Btu/hr-f t-°F 


P 

r 


working fluid Prandtl number 


dimensionless 


P rH 


seawater Prandtl number 


dimensionless 


Dimensions 




d 


tube inside diameter 


ft 


t 


tube wall thickness 


ft 


S T 


tube bank transverse spacing 


ft 


S L 


tube bank longitudinal spacing 


ft 


l 


heat exchanger length 


ft 


w 


heat exchanger width 


ft 


a 


heat exchanger height 


ft 


A 

o 


tube outside area 


ft 2 


A. 

1 


tube inside area 


ft 2 


A 

mw 


tube wall median area 


ft 2 



9 



Heat Exchanger Characteristics 



Units 



area 

U u overall heat transfer coefficient 
n 

number of thermal units 

intermediate performance variable 
n 

9^ rate/capacity ratio 

h outside heat transfer coefficient 

0 

h. inside heat transfer coefficient 

1 

Rp fouling resistance 

R tube wall resistance 

w 

R. inside resistance 

1 

R outside resistance 

o 

N' number of tube rows 

N T total number of tubes 

N u working fluid Nusselt number 

N u seawater Nusselt number 
uH 



Temperatures 



Tp working fluid: exchanger outlet 

T c working fluid: exchanger inlet 

Tr£ hot seawater 
T n _ cold seawater 



Power 

G gross power output 

E net power output 

Wp working fluid pumping power 
Wp seawater pumping power 

Flow parameters 

m working fluid flow rate 

nip seawater flow rate 

G^ working fluid mass flux 

seawater velocity 



Btu/ft 2 -hr-°F 
dimensionless 
dimensionless 
dimensionless 
Btu/ft 2 -hr-°F 
Btu/ft 2 -hr-°F 
ft 2 -hr-°F/Btu 
ft 2 -hr-°F/Btu 
ft 2 -hr-°F/Btu 
ft 2 -hr-°F/Btu 
dimensionless 
dimensionless 
dimensionless 
dimensionless 



°F 

op 

°F 

°F 



MW 

MW 

KW 

KW 



lbm/hr 

lbm/hr 

lbm/hr-ft 2 

ft/hr 



10 



Units 



Flow parameters (cont'd) 

R e ^ seawater Reynolds number 
R g c working fluid Reynolds number 
DP friction head, working fluid 

DPj| friction head, seawater 

f friction factor, working fluid 

f u friction factor, seawater 

n 

Costing Factors 
it profit 

z^ capital cost, heat exchanger 
capital cost 
z^2 capital cost 
Z£ capital cost, all pumps 
COST total zone 1 cost 
p Q market price of power 
C^ capacity-head product 
C^ capacity-head product 

base cost seawater pump 
B£2 base cost working fluid pump 
P^ intermediate cost variable 
P^2 intermediate cost variable 
F^ material factor 
F^2 material factor 
D ^ price index 

Miscellaneous 

^ energy conversion factor 
p working fluid pump efficiency 
n H seawater pump efficiency 
X vector of decision variables 



dimensionless 

dimensionless 

lbf/ft 2 

lbf/ft 2 

dimensionless 

dimensionless 



$ 

$ 

$ 

$ 

$ 

$ 

$-hr/ f t-lbf 
gal-lbf /min-in 2 
gal-lbf /min-in 2 
$ 

$ 

$ 

$ 



dimensionless 

dimensionless 

dimensionless 



MW-hr/lbm-°F 

dimensionless 

dimensionless 

various 



11 



I. INTRODUCTION 



A. BACKGROUND 

The motivation for developing new energy technology, long 
forecast by such researchers as Putnam [1], has now become so 
widely understood as to require no elaboration here. Research 
and development efforts are proceeding on a broad front in 
search of alternatives to the conventional non-renewable fossil 
fuels and potentially hazardous fission processes. 

One class of proposals seeks to extract useful energy 
from sources existing in nature. With the exception of geo- 
thermal energy, virtually all of these rely ultimately on some 
phenomenon associated with receipt by the earth of energy 
radiated from the sun. A sub-class of these "environmental" 
energy systems utilize vapor cycles in mechanizing the 
conversion from the diffuse heat sources found in nature into 
the more concentrated and transportable energy forms required 
in many applications. 




12 



Figure 1 diagrams the fundamental concept upon which these 
environmental vapor power systems depend. Heat is extracted 
from some natural source of elevated temperature (geothermal 
wells, direct solar collectors, hot seawater, etc.) and 
transferred to a working fluid. Devices suitable to the 
application convert the thermodynamically available portion of 
the available heat into other forms of energy, and the 
unavailable energy is rejected to a thermal sink. Both open 
and closed vapor cycles are possible [2], [3] and the products 
of conversion can take many forms , including electricity and 
fuels such as hydrogen, methanol, and ammonia [4]. 

One widely used vapor cycle is the closed Rankine cycle 

[5] , shown schematically in Figure 2. 

In addition to the conservation of chemical fuels, 
certain of the proposed methods of harnessing energy hold 
promise of significant additional advantages. It is expected 
that their effects on the environment will be relatively benign 

[6] , particularly in terms of atmospheric and thermal pollution. 
They would cause no addition to the total heat burden at the 
earth's atmosphere and rely on sources which are continuously 
renewed by natural processes [7]. 

There is another class of vapor power cycles which, 
although not always exploiting environmental energy sources, 
shares enough of the operating characteristics of those that 
do to warrant mention as a group amenable to the type of analy- 
sis discussed in this paper. These are the "bottoming" cycles 
for extracting power from the still energetic discharges of 



13 




FIGURE 2 . Closed Rankine Cycle 



geothermal, nuclear, and chemically fueled plants. Figure 3 
shows two general types of these "waste heat"cycles. 

The essential feature which differentiates both the 
environmental and waste heat vapor systems from conventional 
ones is the relatively low thermal potential within which 
they operate. A consequence of this characteristic is that 
the size scale of all the cycle components is increased in 
comparison with conventional plants. Heat exchange surface 
areas must be enlarged for sufficient heat to be transferred 
through small driving potentials , and with less energy avail- 
able from each unit of fluid circulated, a far greater volume 
rate of working fluid must be cycled. Pumps, pipes, and 
conversion devices such as turbines all grow in size as the 
temperature difference between the source and sink is reduced 
while the energy product is held constant. 

Viewed fundamentally, environmental power systems employ 
technology which has been available for many years. Many 
concepts have been tested with working models or demonstration 
plants, and some are employed presently on a small scale. 
Although significant technical problems arise in connection 
with specific applications, these do not appear to be permanen 
obstacles. Net energy asessments appear favorable and 
questions of material availability and local adverse environ- 
mental effects seem amenable to solution [6]. 

The primary question which will determine when environ- 
mental energy sources will be exploited on a scale large 
enough to significantly affect the energy market is that of 



15 




FIGURE 3. Waste Heat Cycles 



16 



system economics. Although some researchers predict plant 
costs which are currently competitive with conventional 
methods, [9] uncertainties arising from the lack of operating 
experience weaken the claims of these proponents. Until 
economic viability can be conclusively shown, risk aversity 
will act as a strong deterrent to attracting the very large 
amounts of venture capital required. With the private sector 
presently unconvinced, the federal government is undertaking 
the expenditures required for research and development efforts 
[ 10 ] . 



B. THERMOECONOMICS 

Typically, system design and cost studies are conducted 
in a two-step or, at best, iterative process. Designers 
assemble specifications based on technically achievable and 
desirable functional characteristics. They are, of course, 
guided in their design decisions by some measure of intuition 
as to the economic impacts, usually based on prior experience 
with similar programs. The degree of detail in the initial 
specifications presented, in fact, often reflects the confi- 
dence held by the engineers in their economic appraisals. The 
system and component specifications are then subjected to cost 
analysis, prime cost factors are identified, and technical- 
economic trade-offs are suggested. 

The problems arising from this partial separation of the 
design and costing steps are more or less severe according to 
the application. There is a fundamental difficulty in 
communicating the two groups' understandings in a meaningful 



17 



way, a difficulty which increases as the novelty of the design 
situation and hence number of unconstrained design choices 
increases. In their quest for a sophisticated design product, 
engineers may design around some apparently desirable 
parameter, such as a high heat transfer coefficient. Cost 
analysts may take this figure as fixed and address themselves 
to questions of material selection, maintainability, or 
manufacturing tolerances without recognizing that adjusting 
the heat transfer coefficient itself could produce the most 
rewarding cost effects. 

This type of difficulty is most severe when little ex- 
perience is available to guide the engineer's fundamental 
choices, as is true in the case of environmental vapor power 
systems. The small available thermal potential drastically 
distinguishes these systems from their high temperature 
counterparts. In a fuel-fired generating plant, for example, 
the power required to pump the working fluid can be neglected 
in a first approximation, and a variation of 1°F temperature 
difference across a boiler tube is insignificant. As is 
demonstrated later in this study, such considerations can have 
a profound influence on the overall economics of an environ- 
mental plant. 

To some extent, the engineer's problem can be viewed as 
being where to start. Recognizing that pumping power is going 
to be substantial, he might decide to assign 10 or 20 percent 
of the plant's overall output to pumping requirements and 
build much of the rest of the design about this choice. Or 



18 



he might choose to utilize 30 percent of the total temperature 
difference for heat transfer, leaving the remaining 70 percent 
available for enthalpy drop across the turbine. He might 
establish a dimensional constraint, based on nothing much more 
than the feeling that a 100 foot diameter pipe is a very big 
pipe . 

Unf ortunatly , all these basic choices involve performance 
and cost tradeoffs. If flow rates are increased to enhance 
heat transfer, drag coefficients increase as well. How much 
improvement in heat transfer is worth how large an increase in 
pump head, and hence pump work? Pump work is also influenced 
by heat exchanger tube diameter, spacing, and surface charac- 
teristics, which also affect space and material requirements. 
How much should one be willing to pay to reduce fouling heat 
resistance? If heat exchange is dominated by fouling 
resistance, is it worth the extra temperature drop necessary 
to shift to a different boiling regime? Unless the cost 
analyst is knowledgeable about the thermodynamic consequences 
of costing factors he is in as poor a position as the engineer 
to make the tradeoffs in dollars per millimeter of fouling 
organisms . 

C. OBJECTIVE 

What is needed is an analytical method whereby overall 
economic effects may be integrated into engineering design in 
such a way that the designer's intuition may be enhanced in 
trading off the costs and benefits of parameter selection at 
the margin. A means is required for mapping the large number 



19 



of interrelated engineering variables into their individual 
and collective effects in the marketplace, where the ultimate 
design appraisal will take place. 

The research reported on in this paper is intended to 
develop and evaluate one method of integrating marginal 
cost/benefit analysis into engineering design and to show 
the kinds of information which could thus be gained. In this 
initial investigation, no effort has been made to apply the 
method to any particular practical design problem or to 
produce analytical insights into existing systems. The 
intent has been to show how thermoeconomic analysis can be 
performed and what value it can have when applied to a specific 
real case. 



20 



II. THERMOECONOMIC ANALYSTS 



A. CONCEPT 

Profit is the difference between benefits and costs, 
both broadly considered. When these can be related over a 
common set of decision variables, X, one may write 

tt (X) = B(X) - C(X) 

with B(X) representing the sum of all benefits, and C(X) the 
sum of all costs: 

N 

B (X) = $ B . (X) 

1 1 

N 

C(X) = 2 C.(X) 

• 1 
i 

If all the relevant B^ and C^ can be defined functionally 
over X, performing 

maximize: ir 

subject to: a required level of performance (A) 

would produce the desired optimization. 

B. PROBLEM REDUCTION 

Attempting a global optimization directly with all possible 
costs and benefits considered, although theoretically possible, 
encounters many practical difficulties [11]. It is possible, 
however, to achieve considerable reduction of the problem 
without sacrificing many of the benefits of the analysis. 



21 



First, although the impacts of general (and difficult to 
quantify) externalities, such as independence from foreign 
control of energy sources, are important and should not be 
excluded from the final analysis, many interior decisions 
suffer not at all from excluding externalities such as these 
from most of the study. Many other factors are not related 
to the decision variables (X^) and therefore do not affect 
marginal design choices. For example, personnel training 
expenses are not close functions of tube diameter. Since 
the solution to 

maximize it = B(X) - C(X) - D 
subject to g(X) = 0 

where D is constant with respect to X is identical to the 
solution of 

maximize tt = B(X) - C(X) 
subject to gCX) = 0 

any factor which acts only as an additive constant may be 
excluded from the analysis without affecting the results. 

Even with invariants over the decision variables ex- 
cluded, there are other serious impediments to seeking global 
solutions to (A) . Convexity of the optimization problem is 
not assured by the physical relations modeled.^" When all 



A convex optimization problem is defined as one with a 
convex objective function, to be minimized , concave £ inequal- 
ity constraints, and linear equality constraints [12]. The 
conditions on the constraints assure that the feasible region 
is a convex set, i.e., for every X, 0 < X < 1, and any two 
points X-p X£ €T, a convex set, [XX^ + (l-X^^] €T. 



22 



decision variables are considered at once in a global assault 
it is increasingly difficult to test for uniqueness of the 
solution. Secondly, since design variables in one system 
component often are only distantly related to those in another, 
insights are obscured when they are varied simultaneously 
within one code. Thirdly, the model can never be exact. It 
is important for the designer to keep track of the effects 
of his. modeling choices in detail. This is more easily achieved 
by putting the pieces together sequentially than all at once. 
Finally, the designer often has adequate information available 
to intelligently fix some of the variables. It is unnecessary 
to complicate the analysis by including as free variables 
factors which are closely constrained by other considerations. 

For these reasons, it appeared desirable to follow the 
usual procedure for the optimization of large scale systems 
by decomposing the problem into coherent interrelated zones 
and achieving global optimality through one of the available 
zone coordination methods. The next section contains an 
outline of the general procedure. 

C. PROBLEM COORDINATION 

The general theory for optimizing large scale systems 
through coordination of smaller subsystems can be found in 
references such as Wismer [11], The following discussion of 
the two basic approaches is greatly particularized in that 
the terminology and composition of the examples reflect the 
structure of the sample analysis which is presented in section 
III. 



23 



The first approach, called the model coordination method, 
can be understood through consideration of the decomposed 
system shown in Figure 4. 

Define y = (T^,T^) as a vector of coordinating variables 
and X-^ and X^ as vectors of design variables in zones 1 and 2. 
Then construct the zone subproblems: 

minimize: f^(X^,y) 

X i5 y i = 1,2 

subject to: g^(X^,y) >_ 0 
h. (X. ,y ) = 0. 

l l 

The first level of analysis is conducted by setting y = 
y°, a feasible value of y. Then solve 

minimize: f^CX^y 0 ) 

X. i = 1,2 

l ’ 

subject to: g^(X^,y°) >_ 0 
h i (X i ,y°) = 0. 

The solutions are designated X^ and X^. The second level 
of analysis seeks to find the value of y which produces the 
minimum value of 

F(X^, x\ 9 y) = f^xj, y) + f^x], y) 

subject to: g^(X^,y) >_ 0 i = 1,2 

h i (X^,y) = 0. 

Designate the solution by y^. An iterative sequence is 

now established by replacing y° by y"*" in the first level 

. . ~2 ~2 
problems and resolving; using the resulting X^ to find y 



24 



T 



H 




FIGURE 4. Model Coordination 



25 



in the second level problem, and so forth until the improve- 
ment achieved with each iteration is less than a specified 
tolerance . 

This approach is called the model coordination method 
because the task of the second level control is to choose the 
linking variables in such a way that the independent first 
level systems are forced to choose solutions which in fact 
correspond to an overall system optimum. In some references, 
this is called the feasible method. 

The second method, called goal coordination or the dual 
feasible method, views the decomposed system as in Figure 
5 . 

It is important to note that in this formulation of the 
problem, y does not necessarily equal z. The interactions 
have been literally removed by "cutting" all links between 
subsystems . 

The physical requirement that, in the end, y must equal 
z, termed the interaction-balance principle, is satisfied in 
the course of the analysis as follows. 

In the first level analysis, let X =X°. Then solve 



minimize : 


L 1 


«1 


> t h 


•r c -.i°) 


= f l 






subject to: 


Si 


(X 1 


> t h 


>*'c ) i 


0 








h . 
1 


(X 1 


,t h 


,5T C > = 


0 






minimize : 


L 2 


(x 2 


»*H 




= f 2 


<X 2 


)-X°X- H ♦ A° 


subject to: 


§2 


(X 2 


,5T h 


H 

0 

1 V 


0 








h 2 


(X 2 


,h h 


’V - 


0 







26 





T 

l E 


~ 1Xli *T 




f 


ZONE 1 




ZONE 2 




X 1 






x 2 


~1 




h { 








X" c 


i 2j ~ 

C 







FIGURE 5 . Goal Coordination 



Define : 

l - ! T H> T ci 

z = jjr H .x- e j 

X = S x i> x jj 



27 



yielding: X^ , , and y^ . 

The second level problem then becomes choosing A such 
that solutions to the first level problems result in 
satisfaction of the interaction balance principle. This is a 
well behaved optimization in its own right and is solved with 
the usual techniques of mathematical programming. 

Notice that in this method the coordination effect of 
the second level analysis is effected by manipulating the 
goals of the first level analysis through adjustment of the A 
coordinating variables, hence the term goal coordination 
method. The A multipliers enter the individual first-level 
problem objective functions linearly and act like prices, 
adding to or subtracting from the performance function of each 
subproblem in direct proportion (with proper sign) to the amount 
of demanded and the amount of y^ produced. Thus the 
second-level goal coordination can be interpreted as modifying 
"prices" of the interacting variables in order to force the 
independent first-level problems to select consistent values 
of the linking variables and hence the correct overall system 
optimum . 

Much additional information is available in the results 
of the steps of the solution when cast in this format, and the 
interested reader is referred to the considerable literature 
on the subject, [13, 14, 15 and 16, for instance]. 

Because of its more straight forward formulation, the 
sample analysis in the following section is cast in the model 
coordination format. 



28 



III. SAMPLE ANALYSIS 



A. PRELIMINARIES 

The methodology of thermoeconomic analysis can best be 
described through demonstration with a sample analysis. For 
this purpose, an extremely simplified thermal system was 
selected; one which contains the essential features of a 
realistic system but avoids a number of complications which 
would tend to obscure the technique. It should be well under- 
stood that with lumped component representations and several 
significant losses neglected, the model chosen can not be 
treated as representing a practical plant, nor can the 
results of the analysis be taken as having implications for a 
real system. The model does have many similarities with ocean 
thermal energy conversion plants as presently conceived, and 
in Appendix B a discussion is presented as to what refine- 
ments would be necessary to extend the sample model into one 
of a functional ocean thermal system. For ease of exposition, 
the model will be discussed without repeated references to 
these departures from realism. 

B. BASIC SYSTEM DESCRIPTION 

Figure 6 diagrams the basic system considered. The 
thermal source consists of an infinite supply of seawater at 
a temperature of T^ = 85°F. The thermal sink is a similarly 
limitless supply of seawater at T^ = 45 °F. In the energy 
extraction component the ammonia working fluid is heated as 



29 




FIGURE 6 . Basic System 



it flows through the shell side of a rectangular crossflow 
shell and tube heat exchanger with smooth staggered tubes. 
The heat is provided by relatively hot seawater flowing 
through the tubes as shown in Figure 7. 

Single phase heat exchange takes place in the device , 
with both fluids remaining compressed liquids. 

The energy conversion component receives hot ammonia 

liquid from the heater, accomplishes energy conversion to 

electrical form, and discharges the liquid at a lower 

temperature. The manner in which the conversion takes 

place is unspecified and not necessary for this sample 

analysis. The conversion process is described by a single 

parameter, ip , which measures how much energy is converted 

to electricity per pound mass of ammonia flowing through the 

device per degree Fahrenheit temperature drop. The value 

selected for was 0.5 Btu/lbm °F, which is approximately 

half the specific heat for liquid ammonia and, incidentally 

about the same energy available to a turbine with saturated 

. . 2 

vapor inlet conditions. 

The fluid pressurizer consists simply of one or more 
standard centrifugal pumps, sufficient to drive the working 
fluid through the system at the required rate. Both the hot 
and cold seawater are similarily pumped. 



2 

Saturated ammonia vapor at 80 °F has enthalpy of 630 
Btu/lbm. Isentropic expansion to 50°F results in enthalpy 
of 615 Btu/lbm, or 0.5 Btu/lbm per °F [17]. 



31 



AMMONIA 



Ji 



PZ 

w 

Eh 
Eh < 
O ^ 
K < 
W 
cn 




32 



FIGURE 7 . Heat Exchanger 



The system was zoned as depicted in Figure 6, with 
zone 1 consisting of the heat exchanger and working fluid and 
hot seawater pumps , and zone 2 consisting of the energy 
conversion device and the cold seawater pumps. 

Before proceeding further, it should be made clear that 
none of the above assumptions nor those which follow consti- 
tute final arbitrary design selections. Each parameter, 
fluid, and configuration is eventually fixed as an output of 
the analysis itself. Their initial specification should be 
regarded as tentative, pending further information to be 
developed in the course of the study. This preliminary 
configuration acts only as a starting point. 

The next step is to characterize zonal inputs and outputs 
in terms of appropriate physical variables which are descrip- 
tive of the transactions taking place at zone boundaries . 

The principal feature of the hot seawater is its temperature, 
Tr£5 so this was chosen as the input to zone 1 from the thermal 
source. The other input to zone 1 is the ammonia discharge 
from zone 2, which is again described by its temperature, T . 
The output of zone 1 is hot ammonia liquid at temperature T^. 
The only remaining variables which cross zone boundaries are 
the electrical output of zone 2, G, and the cold seawater 
from the thermal sink at temperature T^. 

The global problem is to maximize the profit obtainable 
by selling the system’s electrical output at market prices. 
Translated into zone terms , this implies that each zone should 
produce the required level of output at minimum cost, given 
the inputs it has to work with. 



33 



C. DETAILED DESCRIPTION OF ZONE 1 

The heat exchanger has length in the direction of sea- 
water flow (£), height in the direction of working fluid flow 
(a), and width transverse to each (w) . Tubes have inside 
diameter (d), wall thickness t, and have transverse and 
longitudinal spacing S^, and S^. The inside and outside heat 
flow resistances due to chemical and biological fouling are 
combined into one fouling resistance, Rp. 

Selection of ammonia as the working fluid and seawater 
as the heat source leads to the following table of approx- 
imate physical properties, all considered constant. 



Table III-l. 
FLUID PROPERTIES 



SPECIFIC 



FLUID 


DENSITY 

(lbm/ft3) 


VISCOCITY 
( lbm/ft-hr ) 


CONDUCTIVITY 

(Btu/hr-ft-°F) 


HEAT 

(Btu/lbm°F) 


Ammonia 


p = 40 


V = 0.5616 


K = 0.307 


C = 1.135 
P 


Seawater 


J- 

CD 

II 

m 

Cl 


V - 2.37 


K h = 0.349 


C =1.0 
P 



The working fluid mass flowrate (m) and hot seawater mass 
flowrate (m^) are provided by centrifugal pumps, which deliver 
the required flows against the head created by frictional and 
form losses in the heat exchanger, (minor losses were 
neglected but could easily be included) . The pumping power 
for these pumps, and , is a parasitic deduction from the 
gross plant electrical output, G^. 



34 



Fixing the input, output, and linking variables (T HE , 

^CE’ ^H’ T c’ an< ^ ^ temporarily helps to focus an understand- 
ing of zone 1 objectives and constraints. T^ E and T^ E were 
set previously at 85°F and 45°F, and these define the thermal 
potential available to the system. If half of this potential 
is assigned to drive heat through the exchanger surfaces, 
and T c selections of 75°F and 55°F result. If overall power 
output is set at 25 mw (a frequently encountered figure for 
prototype ocean thermal plants), the required working fluid 
flow rate can now be determined from the relationship 



G = m iKT u -T ) • (1) 

He 

It now becomes evident that the task of zone 1 is to 
receive T^ E and T c and produce the required m at with 
minimum cost. The next major task is to select the design 
variables to be used. To do this, we first look at the 
governing physical and cost relationships. 

As discussed in [18] the performance of a heat exchanger 
can be described in terms of its effectiveness: 



€ = 



T u - T 
H c 

T - T 
HE c 



= 1 - e 



-re 



where 



r = 1 - e 



-NO 



and 



N = 



¥h 

mC 



0 = ” hC p h 

mC 



Alternatively, the amount of heat transferred can be found from 



35 



Q = U H A H AT LM- 

In either case, the fundamental process description is in 
terms of heat exchange surface area, heat exchange coeffic- 
ients, flowrates, temperatures, and fluid properties. 

The major costs in zone 1 are the capital costs of the 
heat exchanger, z^, the pumps, z^, and the cost of the 
pumping power. This latter can be considered as an oppor- 
tunity cost and valued at the amount which could have been 
realized had the parasitic pumping power, and W^, been 
sold at the prevailing rate, p , instead of being used 
internally. Correlations are available [20] which give 
capital costs of heat exchangers as functions of heat 
exchanger area and capital costs of pumps in terms of the 
product of flowrate and head. The frictional head is usually 
determined empirically and related to flow velocities, 

exchanger configuration, and fluid properties in terms of 

3 

Reynolds numbers. 

It might initially appear attractive to choose the 
design variables to be m^, U^, , and the friction heads 

3 

The Reynolds number is a dimensionless grouping of 
physical variables which indicates the ratio of inertia 
forces to viscous forces. It is formed from the product 
of a characteristic velocity times a characteristic 
dimension, divided by the fluid kinematic viscocity [21], 

The Prandtl number is also dimensionless, being a 
measure of the ratio of the diffusivity of momentum to 
the diffusivity of heat. It is formed by multiplying 
the fluid’s specific heat times its viscocity and 
dividing by its conductivity [21]. 



36 



DP and DP^ , but it is at this point that a key feature of 
thermoeconomic analysis comes into force. Recall that what 
is desired is a way to discover the tradeoffs between cost 
and performance. Whatever variables are chosen, it must be 
possible to establish this balance through the functional 
relations over the domain of the variable set. As an 
example of what happens otherwise, consider working with the 
variables suggested just above. Performance can always be 
improved by increasing U^, and it doesn't cost anything to 
do so since is absent from the cost correlation. Costs 
can always be decreased by dropping the DP's, and performance 
would seem to be unaffected because the heat exchange equations 
do not contain pressure drop terms. Any sensible computer 
code would therefore drive and DP as high and low, 
respectively, as is allowed. Setting a constraint on these 
parameters is, in effect, arbitrarily choosing them, and no 
information has been gained in the process. Achieving high 
heat transfer with low pressure drops is known to be 
desirable a priori . 

Besides not permitting a cost-performance balance to be 
weighed, there is a second problem with the variable list 
suggested, namely that and the DP's are inextricably linked 
through the Reynolds numbers. With a given working fluid, 
heat transfer can only be improved by raising the Reynolds 
numbers with the concurrent result that the pressure drops 
are increased simultaneously. This is the core concern of 
the zone 1 analysis: is made up of the inside coefficient, 



37 



h-, the outside coefficient, h , the tube wall conductivity 
and the fouling resistance. There are two pressure drops of 
concern, one in the seawater and one in the working fluid. 

What combination of these parameters will produce the heat 
exchange required at minimum cost? 

To identify an appropriate variable set over which to 
find this cost-performance balance, one must look to the 
next level. Besides physical fluid properties, Reynolds 
numbers depend upon flow rates and spatial dimensions. 

Surface area depends on spatial dimensions. Pump work depends 
on flow rate and pressure drop, which vary as functions of 
Reynolds number. 

Clearly, then, all the cost and performance calculations 
can be built up in terms of flow rates and spatial dimensions , 
and this is the highest level of variable with which the 
desired tradeoff can be made with the functional relationships 
available. Note, however, that if other valid relationships 
could be found which gave the information required in terms of 
other quantities, other variables might be able to be used. 

With the tools at hand, though, it was decided to perform 
the analysis in terms of dimensions and flowrates. But 
variable selection is not yet complete; one has the option of 
which parameters will be allowed to vary independently in the 
code and which will be controlled externally. This question 
is resolved as a matter of judgment, and depends upon the 
confidence the designer has in his preliminary intuition and 
what specific information he seeks from the analysis. Hope- 



38 



fully, this matter will be clarified as the analysis proceeds. 
For the present investigation, it was decided to permit four 
variables to "float": seawater flow rate, and the length, 

height and width of the heat exchanger. The following 
parameter selections were made. Included are those which 
have been discussed previously. 



The functional relationships over both costs and 
performance are developed in detail in Appendix A and summar- 
ized below. 

Pump Work, Working Fluid 



Table III-2. 

SELECTED VALUES OF PARAMETERS 



working fluid: 
tube diameter: 
tube wall thickness: 
tube spacing, S^: 
tube spacing, S. : 



ammonia 



1/2 inch 
0.035 inch 
1.5 d inches 
1.5 d inches 
8 5°F 
7 5 ° F 
55 °F 
2 5 MW 

0.5 Btu/lbm-°F 
0 . 0 3/Kw-hr 
0.9 

0.005 ft 2o F" hr /Btu 
30 Btu/ft-hr-°F 



hot seawater temperature: 
hot working fluid temperature: 
cold working fluid temperature: 
Gross plant power output: 
energy conversion factor, 
market price of energy: 
pump efficiencies: 
fouling heat resistance: 
tube wall conductivity: 



WP = mD £ 



PR 




39